Beilstein J. Org. Chem.2015,11, 817–827, doi:10.3762/bjoc.11.91
systems.
Keywords: molecular rupture mechanism; multivalency; malleability; pyridine coordination compounds; scanningforcemicroscopy; Introduction
In a multivalent molecular system, two partners interact with each other through two or more non-covalent equivalent interaction centers. This principle is
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Graphical Abstract
Figure 1:
Expected coordination complexes of monovalent and bivalent structures (1 and 2a–c, respectively) wi...
Beilstein J. Org. Chem.2014,10, 1372–1382, doi:10.3762/bjoc.10.140
media (Figure 2a,b).
Study of biantennary peptides association using scanningforcemicroscopyScanningforcemicroscopy (SFM) elucidates information not only about the association process both in solution and on a surface, but also about fine details of the formed architectures. Of particular interest
dimensions exceeded the working limit of the instrument, the experiment was stopped.
For experiments with biantennary sialooligoglycines their aqueous (Milli-Q) solutions with a concentration of 0.1 mg/mL were used.
Scanningforcemicroscopy (SFM)
The samples were imaged with a Nanoscope IIIa instrument
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Graphical Abstract
Figure 1:
The structure of biantennary oligoglycines and their glyco derivatives (sp = spacer group).